Selective H<sub>2</sub>S Absorption in Aqueous Tertiary Alkanolamine Solvents: Experimental Measurements and Quantitative Kinetic Model
نویسندگان
چکیده
In the treatment of many fuel gases such as biogas, natural gas, syngas, and so on, tertiary alkanolamines play an important role in selective removal H2S with respect to CO2. The selectivity might be required for various reasons: more stringent specifications, optimize performance Claus unit, lower cost CO2 capture, on. H2S/CO2 is mainly kinetic and, a lesser extent, thermodynamic. A novel experimental setup has been put place measure time evolution simultaneous absorption results extensive campaign 18 different aqueous alkanolamine solvents (13 mol % amine, 87 H2O) are presented. Although expected very fast proton transfer, significant variation rates thus observed. This could not only explained by pKa or viscosity amines. Therefore, accurate quantitative molecular simulations-based model developed validated. study allowed us better understand origin selectivity, well identify amines higher than MDEA (MethylDiEthanolAmine), standard industrial solvent.
منابع مشابه
Modeling and Experimental Study of Carbon Dioxide Absorption into Aqueous Amine Based Solvents
This work focused on the CO2 capture by absorption into amines based absorbents. Aqueous mixtures containing different types of amines (MEA, MDEA, AMP, PZ and PZEA) are experimentally compared in a special gas-liquid contactor (a cables-bundle contactor) with respect to the CO2 removal performances at 25°C and atmospheric pressure. This absorption process was also simulated with the use of publ...
متن کاملSelective binding of L-glutamate derivative in aqueous solvents.
A chiral bisguanidinium macrocycle binds N-Boc-L-glutamate in a 1 : 1 stoichiometry with significant selectivity in competitive solvent (DMSO-H(2)O).
متن کاملPhotodegradation of levofloxacin in aqueous and organic solvents: A kinetic study
perazinyl)-7-oxo-7H-pyrido[1,2,3-de]-1,4-benzoxazine-6-carboxylic acid] (Fig. 1) is a broad spectrum fluoroquinolone antibacterial, which is effective against a wide range of Gram-positive and Gram-negative bacteria (1). Fluoroquinolones are sensitive to light (2) and studies have been carried out on the photodegradation of quinolones (3), fluoroquinolones (4), ciprofloxacin (5, 6), sparfloxaci...
متن کاملCalorimetric Measurements of CO2 Absorption into Aqueous -Methyldiethanolamine Solutions
A reaction calorimeter was used to study the rate and heat effects during CO2 absorption into aqueous solutions of N-methyldiethanolamine (MDEA). The experiments were carried out at constant pressure of 0.1 MPa and 0.3 MPa over a range of temperature from 293 K to 333 K. The amine content changed from 10 to 30 mass %. The experimental equipment and procedure were described with the emphasis on ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Industrial & Engineering Chemistry Research
سال: 2023
ISSN: ['0888-5885', '1520-5045']
DOI: https://doi.org/10.1021/acs.iecr.3c00888